I have tested this out, and have had it done to me, it seems not to have an internal CD, and it is chance to proc per pellet (multi shot weapons like the blast rifle are good for this also). I was able to get multiple procs with a single shotgun blast (highest procs per shot I have gotten was with a Heavy Scatter Gun (12 pellets) and was able to get 4 on a NPC (Blacklung)). I found Syphon being the only thing that makes Combat Shotguns worth it in PvP (15-20 auto shots with Nano, perk that ups the nano chance from crits... I can survive a face to face fight with a Grind Fragger...).
ALSO I have ran into about 2 people in the past 2 days that while damaging them their shields are recharging (no BMGs being used by either side) and Fire nano weapons being used... I THINK its a glitch, and it seemed to be constant for one match, but the fallowing matches I have ran into them they did not have this happening.



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